8/31/2023 0 Comments Jl cmder v1.9.4![]() 1, 2 An under-discussed component of these dramatic events is how the forest recovers once the fire is out. The dramatic impact of forest fires is increasingly visible with frequent reports appearing in the media. Only through successful use of all the components generated during biomass refining, can economic sustainability be potentially achieved. Key results include a highly selective catalytic oxidation reaction, conversion of the resulting ketone to a butenolide by two alternative approaches, a selective acetal reductive opening reaction, X-ray crystallographic analysis of two compounds and detailed comparison of the final products with previous literature reports. Whilst many applications of this co-product stream can be proposed, in this case the major monosaccharides have been converted to relevant karrikins in short reaction sequences. During work to fractionate biomass with the goal of obtaining high quality lignins, an interesting co-product stream derived from the hemicellulose in the biomass, was obtained. This report describes their synthesis from a biomass-derived product stream. ![]() As a result, they are relevant and interesting compounds. Members of the karrikin family of bioactive small molecules are known to promote germination of a range of plants following large scale fires.
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